As ^^^ stated there isnt really a good way to block signals. Well at least that wouldnt cost a ton of money or possibly get you in some trouble with the FCC. If you absolutely needed to shield the room from wifi you would indeed need to make a farraday cage.
If you are not familiar with what that is, you would need to take some fine copper mesh and line the whole room. The mesh will block and disrupt the outside radio signals from wifi, a side effect will be that all other signals are blocked as well such as cell phones, radio, etc.
Overall not very practical to do.