First thanks to all who have commented on this.
After some more research I found that the current wireless link was actually running at 54MBps and quite capable of transfereing data at the same time as VOIP.
Also something no-one mentioned was that I would need a router to be able to get traffic to flow between the two subnets.
With this in mind there was no need for an extra wireless link, just a device to route between the two subnets. I had a look at Cisco routers and some linux software routers, all of which were either very complex to configure or very expensive to buy.
Solution:
I purchased a second network card for a Windows Server 2003 box that only runs a small DB for £5.
I attached the second network to the new network card and installed and configured Routing and Remote Access on the 2k3 box.
Within 5 minutes or so I had traffic flowing between the two companies. Computers on each side can only be accessed by IP address and I am acheiving 20MBps throughput as stated by Ikalmar.
The document control software is alot happier now and is very usable.