Your exchange server will need to have a different domain name (in addition to) your normal domain name.
say that you are
[email protected] and
[email protected], then you could create a new domain like
[email protected]mple.com and setup the exchange server to accept mail for this in additon to the example.com. email.
On the postfix server in a file usually at /etc/postfix/virtual, you have a list of redirects like so...
[email protected] [email protected]mple.com
Then in the transport file
exchange.example.com smtp:[111.222.33.44]
so that postfix knows where to send mail for this new domain