Sorry, that's not possible unless you're switching to a Linux server or distribute the access to more "servers". The half-open TCP connections limit has nothing at all to do with the connection limit imposed by Windows. The former is OSI Layer 4, the latter 5. The connection limit of the client OS has been in place since NT4, the TCP connection limit was only introduced with XP SP2.
Even if it were possible, nobody here would be allowed to help you, because it would be against the EULA.
Switch to a server OS, which has the addiitonal benefit that you can create a domain with centralized user and computer management.
Inbound connections limit in Windows XP
http://support.microsoft.com/kb/314882Troubleshooting Server Message Block inbound connection limit in Windows peer-to-peer workgroup
http://support.microsoft.com/kb/328459