Is the domain name of the server the same as the domain of your corp email addresses you're trying to get to? That would cause any email to those address to stay local on the sendmail server rather than getting sent to the appropriate email server.
Either way, edit your /etc/mail/mailertable file do look like this:
corpdomain.com esmtp:[1.1.1.1]
Where corpdomain.com is the email domain of your corporate email addresses you're trying to get to and 1.1.1.1 is the IP address of the email server that handles mail for that domain (your exchange server or whatever it is). This will override normal mailflow for that domain and force it to be delivered to that IP address.
Then remake the mailertable map:
# makemap hash /etc/mail/mailertable.db < /etc/mail/mailertable
And then restart sendmail.