I'm no postfix expert, but here's what I found:
http://www.irbs.net/internet/postfix/0809/0160.htmlI assume (being careful here!) that if you are allowed to send 100 mails per hour, you could set the parameter "default_destination_rate_
delay" to 36, to make sure there's a gap of 36 seconds in between mails.
And for what it's worth:
http://policyd.sourceforge.net/readme.html