Hi,
Of course it's possible to add a second MX record for the same SMTP suffix but associated to a second DNS CNAME representing your second SMTP server.
But doing that, your second SMTP server will receive incoming e-mails. If your MX records point to several SMTP servers then all these servers will receive incoming mails. DNS mechanisms will do a sort of load balancing on these 2 MX records.
If you don't want second SMTP server to receive incoming emails then MX records is probably not a good solution.
Have a good day.