CAT 6 is backwards compatible with CAT 5 / 5e so yep, if it's the same price you will be future-proofing!
CAT 6e does not actually exist as a standard and is used to market cable which exceeds the current CAT 6 specification in terms of loss, crosstalk and bandwidth. The next ratified standard after CAT 6 is CAT 6A which operates at higher frequencies than CAT 6 - detailed at the bottom of the following page:
http://en.wikipedia.org/wiki/Category_6_cable