Create a group policy in the Organisation unit you require.
The settings are in User Configuration, Windows Settings, Internet Explorer Maintenance, Connection.
I would suggest you create a new OU and move a test user to this OU and create the Group Policy.
To update the Group Policy on the test PC type gpupdate in the command prompt as the refresh time is approx 15mins. When you are happy it is working then apply the settings to the required OU.