route add <target> mask <netmask> <gateway IP> metric <metric cost> if <interface>
Example : route add 10.10.10.0 mask 255.255.255.0 192.168.1.1 metric 1
http://www.itsyourip.com/networking/howto-add-persistent-static-routes-in-windows/
http://www.microsoft.com/resources/documentation/windows/xp/all/proddocs/en-us/sag_tcpip_pro_addstaticroute.mspx?mfr=true
I would recommend adding static routes on your box as you have two network cards ;