Hi tjie,
As hmare said LLC stands for "Logical Link Control". Regarding to your 2nd question. You're not able to see or get LLC info because it's a logical protocol responsible for managing the rate of data transmission between sender and reciever. LLC act as an interface between MAC and Network-Layer (MAC --> LLC --> Network Layer).
Why You can get MAC address?
Because It provides addressing and channel access control mechanisms that make it possible for several terminals or network nodes to communicate within a multipoint network. So, it's make sense to have kind of identification in order to mark all devices connected in the network.